Niobium-94, an isotope of niobium with 41 protons and 53 neutrons, is a critical crossroads in the complex nuclear processes that forge heavy elements under the intense pressures and temperatures of dying stars. In an article published in Physical Review Letters, the n_TOF Collaboration reports the first-ever measurement of the probability of niobium-94 taking one of the paths at this crossroads—that is, undergoing neutron capture.